Dimethyl 6-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxylate

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Dimethyl 6-acetyl-2-methyl-1,2-dihydroquinoline-2,4-dicarboxyl­ate

In the title compound, C(16)H(17)NO(5), the dihydro-pyridine ring adopts a sofa conformation. In the crystal, inter-molecular N-H⋯O hydrogen bonds link the mol-ecules into chains running along the b axis.

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Dimethyl 2,6,8-trimethyl-1,2-dihydroquinoline-2,4-dicarboxylate

The title compound, C(16)H(19)NO(4), the hydrogenated ring adopts a twisted conformation. In the crystal, inter-molecular C-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric R(2) (2)(10) dimers. These dimers are further connected via inter-molecular N-H⋯O hydrogen bonds, forming infinite double chains along [001].

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Dimethyl 8-acetyl-2-methyl-1,2-dihydro­quinoline-2,4-dicarboxyl­ate

In the title compound, C(16)H(17)NO(5), the six-membered N-containing ring has a half-boat form; the spiro C atom deviates by 0.34 (2) Å from the plane (r.m.s. deviation = 0.051 Å) defined by the N and four aromatic C atoms. Intra-molecular N-H⋯O hydrogen bonding generates an S(6) ring motif and the dihedral angle between the mean plane though the S(6) ring and that through the five-atom half-b...

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Bis(3-acetyl-6-methyl-2-oxo-2H-pyran-4-olato)bis­(dimethyl sulfoxide)nickel(II)

In the title compound, [Ni(C(8)H(7)O(4))(2){(CH(3))(2)SO}(2)], the Ni(II) atom is located on a crystallographic centre of symmetry and has a distorted octa-hedral coordination geometry of type MO(6). The bidentate dehydro-acetic acid (DHA) ligands occupy the equatorial plane of the complex in a trans configuration, and the dimethyl sulfoxide (DMSO) ligands are weakly coordinated through their O...

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3-Acetyl-6-chloro-2-methyl-4-phenyl­quinolinium perchlorate

In the title mol-ecular salt, C(18)H(15)ClNO(+)·ClO(4) (-), the quinolin-ium ring system is approximately planar, with a maximum deviation of 0.027 (1) Å. The dihedral angle formed between the mean planes of the quinolinium ring system and the benzene ring is 78.46 (3)°. In the crystal structure, inter-molecular N-H⋯O and C-H⋯O hydrogen bonds link the cations and anions into a three-dimensional...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2012

ISSN: 1600-5368

DOI: 10.1107/s1600536812003650